7524838, 7527838, 7533838, 7538838, 7548838, 7555838, 7564838, 7565838, 7570838, 7... Page 1 of 6 ... Page 1 of 6 Material Safety Data Sheet 24 Hour Assistance: 1-847-367-7700 Rust-Oleum Corp. www.rustoleum.com Rust-Oleum Professional High Product Name: Revision Date: 02/23/2009 Performance Enamel Aerosol Section 1 - Chemical Product / Company Information Identification Number: 7524838, 7527838, 7533838, 7538838, 7548838, 7555838, 7564838, 7565838, 7570838, 7578838, 7579838, 7581838, 7587838, 7592838, 239107, 239108, 239109, 239110, 239111, 239112 Product Use/Class: Topcoat/Aerosols Supplier: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Manufacturer: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Preparer: Regulatory Department Section 2 - Composition / Information On Ingredients Chemical Name CAS Number Weight % Less ThanACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA PEL-CEILING Magnesium Silicate 14807-96-6 40.0 10 mg/m3 N.E. 15 mg/m3 N.E. Acetone 67-64-1 30.0 500 ppm 750 ppm 750 ppm N.E. Liquefied Petroleum Gas 68476-86-8 30.0 1000 ppm N.E. 1000 ppm N.E. Xylene 1330 -20-7 25.0 100 ppm 150 ppm 100 ppm N.E. Titanium Dioxide 13463-67-7 15.0 10 mg/m3 N.E. 10 mg/m3 N.E. n-Butyl Acetate 123-86 -4 10.0 150 ppm 200 ppm 150 ppm N.E. Methyl Ethyl Ketone 78-93-3 10.0 200 ppm 300 ppm 200 ppm N.E. Ethylbenzene 100-41 -4 10.0 100 ppm 125 ppm 100 ppm N.E. Toluene 108-88 -3 5.0 20 ppm 150 ppm 200 ppm 300 ppm Ethylene Glycol Monobutyl Ether 111-76 -2 5.0 20 ppm N.E. 50 ppm N.E. Pigment Black 7 1333 -86-4 5.0 3.5 mg/m3 N.E. 3.5 mg/m3 N.E. Stoddard Solvents 8052 -41-3 5.0 100 ppm N.E. 500 ppm N.E. Aromatic Hydrocarbon 64742-95-6 5.0 N.E. N.E. N.E. N.E. 1,2,4-Trimethylbenzene 95-63-6 5.0 25 ppm N.E. N.E. N.E. Chlorite 14998-27-7 5.0 N.E. N.E. N.E. N.E. Pigment Yellow 17 4531 -49-1 5.0 2 mg/m3 N.E. 5 mg/m3 N.E. Quartz (Crystalline Silica) 14808-60-7 1.0 0.025 mg/m3 N.E. 0.10 mg/m3 N.E. Section 3 - Hazards Identification *** Emergency Overview ***: Contains Aromatic Distillate, which may cause cancer. Contents Under Pressure. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. Harmful if swallowed. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Effects Of Overexposure - Eye Contact: Causes eye irritation. Effects Of Overexposure - Skin Contact: May be harmful if absorbed through skin. Prolonged or repeated contact may cause skin irritation. Substance may cause slight skin irritation. Effects Of Overexposure -Inhalation: High vapor concentrations are irritating to the eyes, nose, throat and lungs. 7524838, 7527838, 7533838, 7538838, 7548838, 7555838, 7564838, 7565838, 7570838, 7... Page 2 of 6 ... Page 2 of 6 Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing vapors or mists. Effects Of Overexposure - Ingestion: Aspiration hazard if swallowed; can enter lungs and cause damage. Substance may be harmful if swallowed. Effects Of Overexposure - Chronic Hazards: IARC lists Ethylbenzene as a possible human carcinogen (group 2B). Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. Significant exposure is not anticipated during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. Overexposure to toluene in laboratory animals has been associated with liver abnormalities, kidney, lung and spleen damage. Effects in humans have included liver and cardiac abnormalities. Overexposure to methyl ethyl ketone in laboratory animals has been associated with liver abnormalities, kidney and lung damage. Fetotoxic/embryotoxic effects from inhalation have been seen in rats exposed to >1000ppm during gestation. Contains carbon black. Chronic inflammation, lung fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of time to excessive concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other animal species (i.e., mouse and hamster) under similar circumstances and study conditions. Epidemiological studies of North American workers show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black. Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified as a human carcinogen" by the American Conference of Governmental Industrial Hygienists. Significant exposure is not anticipated during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of carbon black in the formula. Contains crystalline silica as silicon dioxide. Excessive inhalation of respirable crystalline silica dust may cause lung disease, silicosis or lung cancer. Significant exposure is not anticipated during brush or trowel application or drying. Risk of overexposure depends on the duration and level of exposure to dust from repeated sanding of surfaces, mechanical abrasion or spray mist and actual concentration of crystalline silica in the formula. Crystalline silica is listed as Group 1 "carcinogenic to humans" by the International Agency for Research on Cancer (IARC,) and Group 2, "reasonably anticipated to be a carcinogen" by the National Toxicology Program (NTP) Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact Section 4 - First Aid Measures First Aid - Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. First Aid - Skin Contact: Wash with soap and water. Get medical attention if irritation develops or persists. First Aid - Inhalation: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. First Aid - Ingestion: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. Section 5 -Fire Fighting Measures 7524838, 7527838, 7533838, 7538838, 7548838, 7555838, 7564838, 7565838, 7570838, 7... Page 3 of 6 ... Page 3 of 6 Flash Point: -156 F LOWER EXPLOSIVE LIMIT: 0.7 % (Setaflash) UPPER EXPLOSIVE LIMIT : 32.5 % Extinguishing Media: Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: Water spray may be ineffective. FLASH POINT IS LESS THAN 20 °. F. EXTREMELY FLAMMABLE LIQUID AND VAPOR! Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. Special Firefighting Procedures: Evacuate area and fight fire from a safe distance. Section 6 -Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Section 7 -Handling And Storage Handling: Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing vapor or mist. Wash thoroughly after handling. Use only in a well-ventilated area. Wash hands before eating. Storage: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Contents under pressure. Do not expose to heat or store above 120 ° F. Section 8 -Exposure Controls / Personal Protection Engineering Controls: Prevent build-up of vapors by opening all doors and windows to achieve cross -ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Respiratory Protection: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide adequate protection. Skin Protection: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. Eye Protection: Use safety eyewear designed to protect against splash of liquids. Other protective equipment: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. 7524838, 7527838, 7533838, 7538838, 7548838, 7555838, 7564838, 7565838, 7570838, 7... Page 4 of 6 ... Page 4 of 6 Hygienic Practices: Wash thoroughly with soap and water before eating, drinking or smoking. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Appearance: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: -34 -900 F Solvent Like Liquid Slight N.D. N.D. Liquid Vapor Density: Odor Threshold: Evaporation Rate: Specific Gravity: PH: Heavier than air N.E. Faster than Ether N.A. N.A. (See section 16 for abbreviation legend) Section 10 -Stability And Reactivity Conditions To Avoid: Avoid temperatures above 120 ° F. Avoid all possible sources of ignition. Incompatibility: Incompatible with strong oxidizing agents, strong acids and strong alkalies. Hazardous Decomposition: When heated to decomposition, it emits acrid smoke and irritating fumes. By open flame, carbon monoxide and carbon dioxide. Hazardous Polymerization: Will not occur under normal conditions. Stability: This product is stable under normal storage conditions. Section 11 -Toxicological Information Product LD50: N.D. Product LC50: N.D. Chemical Name LD50 LC50 Magnesium Silicate N.E. TCLo: 11 mg/m3 (Inhalation) Acetone 5800 mg/kg (Rat) 50100 mg/m3 (Rat, 8Hr) Liquefied Petroleum Gas N.E. N.E. Xylene 4300 mg/kg (Rat, Oral) 5000 ppm (Rat, Inhalation, 4Hr) Titanium Dioxide >7500 mg/kg (Rat, Oral) N.E. n-Butyl Acetate 13100 mg/kg (Rat, Oral) 2000 ppm (Rat, Inhalation, 4 Hr) Methyl Ethyl Ketone N.E. N.E. Ethylbenzene 3500 mg/kg (Rat, Oral) N.E. Toluene 636 mg/kg (Rat, Oral) >26700 ppm (Rat, Inhalation, 1Hr) Ethylene Glycol Monobutyl Ether 1519 mg/kg (Mouse, Oral)700 ppm (Rat, Inhalation, 7Hr) Pigment Black 7 >8000 mg/kg (Rat, Oral) N.E. Stoddard Solvents N.E. N.E. Aromatic Hydrocarbon N.E. N.E. 1,2,4-Trimethylbenzene N.E. 18000 mg/m3 (Rat, 4Hr) Chlorite N.E. N.E. Pigment Yellow 17 N.E. N.E. Quartz (Crystalline Silica) N.E. N.E. Section 12 - Ecological Information 7524838, 7527838, 7533838, 7538838, 7548838, 7555838, 7564838, 7565838, 7570838, 7... Page 5 of 6 ... Page 5 of 6 Ecological Information: Product is a mixture of listed components. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems. Section 14 - Transportation Information DOT Proper Shipping Name: Aerosol Packing Group: N.A. DOT Technical Name: N.A. Hazard Subclass: N.A. DOT Hazard Class: 2.1 Resp. Guide Page: 126 DOT UN/NA Number: UN1950 Section 15 - Regulatory Information CERCLA - SARA Hazard Category This product has been reviewed according to the EPA "Hazard Categories" promulgated under Sections 311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD, PRESSURIZED GAS HAZARD SARA Section 313: Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS Number Xylene 1330-20-7 Methyl Ethyl Ketone 78-93-3 Ethylbenzene 100-41-4 Toluene 108-88-3 Ethylene Glycol Monobutyl Ether 111-76-2 1,2,4-Trimethylbenzene 95-63-6 Toxic Substances Control Act: Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of TSCA 12(B) if exported from the United States: None known U.S. State Regulations: As follows New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product. Chemical Name CAS Number 7524838, 7527838, 7533838, 7538838, 7548838, 7555838, 7564838, 7565838, 7570838, 7... Page 6 of 6 ... Page 6 of 6 Alkyd Resin PROPRIETARY Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%. Chemical Name Alkyd Resin Alkyd Resin Calcium Carbonate Barium Sulfate CAS Number PROPRIETARY PROPRIETARY 1317-65-3 7727-43-7 California Proposition 65: WARNING! This product contains a chemical(s) known by the State of California to cause cancer. WARNING! This product contains a chemical(s) known to the State of California to cause birth defects or other reproductive harm. International Regulations: As follows CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. CANADIAN WHMIS CLASS: AB5, D2A, D2B Section 16 - Other Information HMIS Ratings: Health: 2* Flammability: 4 Reactivity: 0 Personal Protection: X REASON FOR REVISION: Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations.